Multi-bed type oxidation reactor applied to the coal mine ventilation air methane

Authors

Abstract

The utilization of coal mine ventilation air methane played an important role in saving energy, reducing pollution, improving the safety in coal mine production and adjusting the energy structure. The thermal flow-reversal reactor is one of the main technologies of ventilation air methane utilization which is at a critical stage of industrial application. The thermal flow-reversal reactor of MEGTEC company and designed by some Chinese scholars were used a two-bed type generally. However, the gas who was detained in oxidation chamber and reversal valves will not enter the combustion chamber but through the chimney into the atmosphere directly when switching the flow direction, the average oxidation rate of reactor will be reduced due to the residual gas.

In order to solve the problems including low oxidation rate of methane, pressure build-up of main fan and high failure rate of valves in existing two-bed type oxidation reactor of coal mine ventilation air methane, an innovative structure with multi-bed type oxidation reactor has been designed. The paper analyzes the unique advantages of multi-bed type oxidation reactor by elaborating on the working principles of three-bed and five-bed type device. In the design of the oxidation device for industrial demonstration projects, the device whose processing capacity is 100000 m3/h adopts the five-bed type structure from the aspects of methane oxidation rate, waste heat utilization effect, cost and so on, the thermodynamic calculation process of regenerative chamber as the core unit of the oxidation device is described in this paper.

The technology has an industrial demonstration project whose reactor uses a five-bed type design located in Chongqing Songzao Datong No.1 mine. This project can produce superheated steam 64800t and reduce emissions of CO2 equivalent 107000t annually, the excellent energy-saving and emission reduction benefits should be obtained in the project.

References

Kang, J.D., Lan, B. and Zou, W.F. (2015). Design and application on five-bed type thermal accumulation oxidized device of mine ventilation air methane. Coal Science and Technology, Volume 43, No. 2, pp. 136–139.

Zheng, B., Liu, Y.Q. and Liu, R.X. (2009). Oxidation of coal mine ventilation methane of thermal flow-reversal reactor. Journal of China Coal Society, Volume 34, No. 11, pp. 1475–1478.

Gosiewski, K., Pawlaczyk, A. and Warmuzinski, K. (2009). A study on thermal combustion of lean methane-air mixtures: simplified reaction mechanism and kinetic equations. Chemical Engineering Journal, Volume 154, pp. 9–16.

Lv, Y., Jiang, F. and Xiao, Y.H. (2011). Experimental study of coal mine ventilation methane oxidization. Journal of China Coal Society, Volume 36, No. 6, pp. 973–977.

Gosiewski, K. and Warmuzinski, K. (2007). Effect of the mode of heat withdrawal on the asymmetry of temperature profiles in reverse-flow reactors. Catalytic combustion of methane as a test case. Chemical Engineering Science, Volume 62, pp. 2679–2689.

Xiao, Q., Deng, H.X. and Lv, Y. (2012). Lean methane-air premixed-gas heating process research. Journal of Mining & Safety Engineering, Volume 29, No. 2, pp. 295–300.

Wang, P.F. (2012). Study on theory and experiment of thermal flow-reversal oxidation of coal mine ventilation air methane. Central South University, Hunan, China.

Feng, T., Wang, P.F. and Hao, X.L. (2012). Experimental study on thermal flow-reversal oxidation of coal mine ventilation air low concentration methane. China Safety Science Journal, Volume 22, No. 10, pp. 88–93.

Zhou, X. (2009). Experiment study of coal mine ventilation air methane oxidation. Institute of Engineering Thermophysics Chinese Academy of Science, Beijing, China.

Deng, H.X., Xiao, Q. and Xiao, Y.H. (2014). Design method of thermal flow-reversal reactor for ventilation air methane based on regenerative heat exchange model. Journal of China Coal Society, Volume 39, No. 7, pp. 1302–1308.

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Published

2016-11-28

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Section

Part 2 Technology